Dr Jean-Marc VINCENT
Directeur de Recherche au CNRS (DR2)

Email : jm.vincent@ism.u-bordeaux1.fr

Groupe Nanostructures Organique (responsable)
Institut des Sciences Moléculaires
UMR - CNRS 5255
351 Cours de la Libération
F-33405 Talence Cedex

Tél : 33 (0)5 40 00 89 42
Fax : 33 (0)5 40 00 61 58


Titres et grades universitaires :

1992 : DEA Chimie Moléculaire, Université Joseph Fourier, Grenoble.

1995 : Doctorat de Chimie Organique de l’Université Joseph Fourier, Grenoble. (Directeurs de thèse : M. Fontecave, S. Ménage)

2005 : Habilitation à Diriger des Recherches soutenue le 27 janvier 2005 à l’Université Bordeaux 1.


Postes occupés :

1996-97 : Post-doc au Lawrence Berkeley National Laboratory (EU, Pr R. H. Fish)

1997 : Chargé de Recherche au CNRS à l’Institut des Sciences Moléculaires

2008-2015 : Directeur du groupe Nanostructures Organiques

2010 : Directeur de Recherche CNRS


Thèmes de Recherche :

Chimie de coordination et chimie supramoléculaire dans/sur les phases perfluoré :
Mise au point de méthodologies d’immobilisation de complexes de coordination dans les perfluorocarbures. Applications à la catalyse, la détection/titration d’analytes et aux extractions sélectives. Développement de gélifiants des perfluorocarbures. Modifications de surfaces (SiO₂, téflon) par adsorption de complexes de cuivre fluorés.

Catalyse au cuivre :
Développement de précatalyseurs au cuivre(II) photoréductibles pour des applications en catalyse au cuivre(I), en particulier pour la chimie click (ANR-13-BS07-0006-01, project “PET-Cat” 2013-2017)
Développement de catalyseurs au cuivre(I/II) pour les réactions d’oxydation, addition et polymérisation par transfert radicalaire d’atomes et polymérisation radicalaire, et chimie click.

Réactions photo-induites :
Développement de réactions photosensibilisées par des cétones aromatiques.

Organocatalyse asymétrique :
Réactions d’aldolisations par des dérivés de la proline pour des applications en synthèse de de produits naturels et leurs dérivés, et la synthèse de polymères.


Principales Publications :

Benzophenone vs. copper/benzophenone in light-promoted atom transfer radical additions (ATRAs): Highly effective iodoperfluoroalkylation of alkenes/alkynes and mechanistic studies
R. Beniazza, R. Atkinson, C. Absalon, F. Castet, S. A. Denisov, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
Adv. Synth. Catal., 2016, 358, 2949-2961.

A fluorosurfactant and photoreducible CuII-tren click catalyst: surfactant and catalytic properties at liquid/liquid interfaces
Q. Jochyms, P. Guillot, E. Mignard,* J.-M. Vincent*
Dalton Trans., 2015, 44, 19700-19707 (Invitation themed issue on “Fluorine”, guest Ed. J. Love)

Effective ascorbate-free and photolatent click reactions in water using a photoreducible copper(II)-ethylenediamine precatalyst
R. Beniazza, N. Bayo, F. Molton, C. Duboc, S. Massip, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
Beilstein J. Org. Chem., 2015, 11, 1950-1959. (Invitation thematic series “Copper catalysis in organic synthesis”, guest Ed. S. R. Chemler)

Copper(I)-photocatalyzed trifluoromethylation of alkenes
R. Beniazza, F. Molton, C. Duboc, A. Tron, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
Chem. Commun., 2015, 51, 9571-9574.

Fluorosurfactants for application in catalysis
Q. Jochyms, E. Mignard,* J.-M. Vincent*
J. Fluor. Chem., 2015, 177, 11-18. (Mini-review, invitation special issue “Fluorine in Soft Matter Science”, guest Ed. M.-P. Krafft)

Sunlight-driven copper-catalyst activation applied to photolatent click chemistry
R. Beniazza, R. Lambert, L. Harmand, F. Molton, C. Duboc, S. Denisov, G. Jonusauskas, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
Chem. Eur. J., 2014, 20, 13181-13187. (“Hot Paper”)

Organocatalyzed step-growth polymerization through desymmetrization of cyclic anhydrides: Synthesis of chiral polyesters
A. Martin, F. Robert, D. Taton, H. Cramail,* J.-M. Vincent,* Y. Landais,*
Chem. Eur. J., 2014, 20, 11946-11953.

Polyaldol synthesis by direct organocatalyzed crossed polymerization of bis(ketones) and bis(aldehydes)
N. Liu, A. Martin, F. Robert, J.-M. Vincent,* Y. Landais,* J. Vignolle, H. Cramail,* D. Taton*
Macromolecules, 2014, 47, 525-533.
One-pot synthesis and PEGylation of hyperbranched polyacetals with e degree of branching of 100%
N. Liu, J. Vignolle,* J.-M. Vincent, F. Robert, Y. Landais, H. Cramail, D. Taton*
Macromolecules, 2014, 47, 1532-1542.

A Photoreducible Copper(II)-tren Complex of Practical Value: Generation of a Highly Reactive Click Catalyst
L. Harmand, R. Lambert, L. Scarpantonio, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
Chem. Eur. J., 2013, 19, 16231-16329.

Organocatalyzed Aldol Reaction Between Pyridine-2-carbaldehydes and α-Ketoacids. A Straightforward Route Toward Indolizidines and Isotetronic Acids
V. Liautard, D. Jardel, C. Davies, M. Berlande, T. Buffeteau, D. Cavagnat, F. Robert,* J.-M. Vincent*, Y. Landais*
Chem. Eur. J., 2013, 19, 14532-14539.

Recent advances of fluorous chemistry in material sciences
J.-M Vincent
Chem. Commun., 2012, 48, 11382. (“Feature Article”)

Copper catalyst activation driven by photoinduced electron transfer: A prototype photolatent click catalyst
L. Harmand, S. Cadet, B. Kauffmann, L. Scarpantino, P. Batat, G. Jonusauskas, D. Lastécouères, J.-M. Vincent*
Angew. Chem. Int. Ed., 2012, 51, 7137. (“Very Important Paper”)

Huisgen click cycloaddition from a copper(II)-tren precatalyst without external sacrificial reductant
L. Harmand, M.-H. Lescure, N. Candelon, M. Duttine, D. Lastécouères, J.-M. Vincent*
Tetrahedron Lett., 2012, 53, 1417.

Fluorous catalysis: From the origin to recent advances
J.-M. Vincent
Top. Curr. Chem, 2012, 308, 153.

A fluorous copper(II)-carboxylate complex which magnetically and reversibly responds to humidity in the solid state
A. Motreff , R. Correa da Costa , H. Allouchi , M. Duttine , C. Mathonière , C. Duboc , J.-M. Vincent,*
J. Fluor. Chem., 2012, 134, 49. (Invitation numéro spécial “Chimie du fluor en France”).

Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)₃]²⁺ driven by supramolecular heteromeric fluorous carboxylate-carboxylic acid H-bond interaction
R. Corrêa da Costa, T. Buffeteau, A. Del Guerzo, N. McClenaghan, J.-M. Vincent*
Chem. Commun., 2011, 47, 8250.

Self-adaptive hydrophilic and coordinating Teflon surfaces through a straightforward physisorption process
A. Motreff, C. Belin, R. Correa da Costa, M. El Bakkari, J.-M. Vincent*
Chem. Commun. , 2010, 46, 6261. (“hot article”).

Chemisorption of fluorous copper(II)-carboxylates complexes on SiO₂ surfaces: Versatile binding layers applied to the preparation of porphyrin monolayers
A. Motreff, G. Raffy, A. Del Guerzo, C. Belin, M. Dussauze, V. Rodriguez, J.-M. Vincent*
Chem. Commun., 2010, 46, 2617.

A triblock fluorous surfactant as a specific gelator for perfluorocarbons
J. Gan, M. El Bakkari, C. Belin, C. Margottin, P. Godard, J.-L. Pozzo,* J.-M. Vincent*
Chem. Commun., 2009, 5133.

Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)-carboxylate complex
A Motreff, R. Correa da Costa, H. Allouchi, M. Duttine, C. Mathonière, C. Duboc, J.-M. Vincent*
Inorg. Chem., 2009, 48, 5623.

Noncovalent associations in fluorous fluids (mini-revue)
J.-M. Vincent
J. Fluor. Chem. 2008, 129, 903. (Invitation pour un numéro spécial en l’honneur de D. P. Curran).

A highly active and reusable copper(I)-tren catalyst for the "click" 1,3-dipolar cycloaddition of azides and alkynes
N. Candelon, D. Lastécouères, A. Khadri Diallo, J. Ruiz Aranzaes, D. Astruc, J.-M. Vincent*
Chem. Commun., 2008, 741.

A Copper(II)-Based Multiphasic Fluorous Colorimetric Ethanol Assay
M. El Bakkari, R. Luguya, R. Correa da Costa, J.-M. Vincent
New. J. Chem., 2008, 32, 193. ("hot article" avec commentaire éditorial et couverture).

A concise organocatalytic and enantioselective synthesis of isotetronic acids
J.-M. Vincent*, C. Margottin, M. Berlande, D. Cavagnat, T. Buffeteau, Y. Landais*
Chem. Commun., 2007, 4782.

Benzoimidazole-pyrrolidine/H+ (BIP/H+), a highly reactive organocatalyst for asymmetric processes
E. Lacoste, E. Vaicque, M. Berlande, I. Pianet, J.-M. Vincent,* Y. Landais*
Eur. J. Org. Chem., 2007, 167. (Top 10 most-accessed article of the month).

Reversible fluorous phase-switching of pyridyl-tagged porphyrins : Application to the sensing of histamine in water
J. Fluor. Chem., 2006, 127, 4-5, 558. (Invitation numéro spécial : Current Frontiers of fluoroorganic chemistry and recent advances in fluorous chemistry, Eds : D. P. Curran, K. Mikami, V. A. Soloshonok).

Fluorous catalysis
D. Lastécouères, J.-M. Vincent*
Chemistry Today, 2006, 24, 3, 36-39. (Invitation : "Focus on fluorine chemistry").

Fluorocarbon soluble copper(II) carboxylate complexes with non-fluorinated nitrogen ligands as precatalysts for the oxidation of alkenols ans alcohols under fluorous biphasic or thermomorphic modes : Structural and mechanistic aspects
M. Contel,* P. R. Villuendas, J. Fernandez-Gallardo, P. J. Alonso, J.-M. Vincent,* R. H. Fish*
Inorg. Chem., 2005, 44, 9771.

Benzoimidazole-pyrrolidine (BIP), a highly reactive chiral organocatalyst for aldol process
E. Lacoste, Y. Landais,* K. Schenk, J.-B. Verlhac, J.-M. Vincent*
Tet. Lett., 2004, 45, 8035.

Fluorous phase-switching of pyridyl-tagged substrates/products
M. El Bakkari, J.-M. Vincent*
Org. Lett., 2004, 6, 2765.

Closer to the « ideal recoverable catalyst” for atom transfer radical polymerisation using a molecular non-fluorous thermomorphic system
G. Barré, D. Taton, D. Lastécouères, J.-M. Vincent*
J. Am. Chem. Soc., 2004, 126, 7764.

Isomerization dynamics in homo- and heterochiral atropoisomer copper(I) diimine complexes : A 2D EXSY NMR study
I. Pianet,* J.-M. Vincent*
Inorg. Chem., 2004, 43, 2947.

The pyridyl-tag strategy applied to the hydrocarbon/perfluorocarbon phase-switching of a porphyrin and a fullerene
M. El Bakkari, N. McClenaghan, J.-M. Vincent*
J. Am. Chem. Soc., 2002, 124, 12942.