VINCENT Jean-Marc



    Dernière modification : 26 novembre 2020

  • Dr Jean-Marc VINCENT
    Directeur de Recherche au CNRS (DR2)

    Email : jean-marc.vincent@u-bordeaux.fr

    Groupe Nanostructures Organique (responsable)
    Institut des Sciences Moléculaires
    UMR - CNRS 5255
    351 Cours de la Libération
    F-33405 Talence Cedex

    Tél : 33 (0)5 40 00 89 42
    Fax : 33 (0)5 40 00 61 58


    Titres et grades universitaires :

    1992 : DEA Chimie Moléculaire, Université Joseph Fourier, Grenoble.

    1995 : Doctorat de Chimie Organique de l’Université Joseph Fourier, Grenoble. (Directeurs de thèse : M. Fontecave, S. Ménage)

    2005 : Habilitation à Diriger des Recherches soutenue le 27 janvier 2005 à l’Université Bordeaux 1.


    Postes occupés :

    1996-97 : Post-doc au Lawrence Berkeley National Laboratory (EU, Pr R. H. Fish)

    1997 : Chargé de Recherche au CNRS à l’Institut des Sciences Moléculaires

    2008-2015 : Directeur du groupe Nanostructures Organiques

    2010 : Directeur de Recherche CNRS


    Thèmes de Recherche :

    Chimie de coordination et chimie supramoléculaire dans/sur les phases perfluoré :
    Mise au point de méthodologies d’immobilisation de complexes de coordination dans les perfluorocarbures. Applications à la catalyse, la détection/titration d’analytes et aux extractions sélectives. Développement de gélifiants des perfluorocarbures. Modifications de surfaces (SiO2, téflon) par adsorption de complexes de cuivre fluorés.

    Catalyse au cuivre :
    Développement de précatalyseurs au cuivre(II) photoréductibles pour des applications en catalyse au cuivre(I), en particulier pour la chimie click (ANR-13-BS07-0006-01, project “PET-Cat” 2013-2017)
    Développement de catalyseurs au cuivre(I/II) pour les réactions d’oxydation, addition et polymérisation par transfert radicalaire d’atomes et polymérisation radicalaire, et chimie click.

    Réactions photo-induites :
    Développement de réactions photosensibilisées par des cétones aromatiques.

    Organocatalyse asymétrique :
    Réactions d’aldolisations par des dérivés de la proline pour des applications en synthèse de de produits naturels et leurs dérivés, et la synthèse de polymères.


    Principales Publications :

    A bis-acridinium macrocycle as multi-responsive receptor and selective phase transfer agent of perylene
    J. Hu, J. S. Ward, A. Chaumont, K. Rissanen, J.-M. Vincent,* V. Heitz,* H.-P. Jacquot de Rouville*
    Angew. Chem. Int. Ed., 2020, doi:10.1002/anie.202009212.

    A fluorous sodium L-prolinate derivative as low molecular weight gelator for perfluorocarbons
    R. Beniazza, N. Bayo, D. Jardel, R. Rust, B. Mao,T. Divoux, M. Schmutz, F. Castet, G. Raffy, A. ́Del Guerzo, N. D. McClenaghan, T. Buffeteau, J.-M. Vincent*
    Chem. Commun., 2020, 56, 8655-8658.
    https://pubs.rsc.org/en/content/art...

    Dual benzophenone/copper photocatalyzed Giese-type alkylation of C(sp3)−H bonds
    Abadie, B., J. Damien, G. Pozzi, P. Toullec,* J.-M. Vincent*
    Chem. Eur. J., 2019, 25, 16120-16127. (“Hot Paper”)
    https://chemistry-europe.onlinelibr...

    How the Horvath’ paradigm, Fluorous Biphasic Catalysis, affected oxidation chemistry : Successes, challenges, and a sustainable future
    J.-M. Vincent, M. Contel, G. Pozzi, R. H. Fish
    Coord. Chem. Rev., 2019, 380, 584-599.
    https://www.sciencedirect.com/scien...

    Unexpected surface interactions between fluorocarbons and hybrid organic inorganic perovskites evidenced by PM-IRRAS and their application towards tuning the surface potential
    S. Sadhu, K. Aqueche, T. Buffeteau, J.-M. Vincent, L. Hirsch,* D. M. Bassani*
    Mater. Horiz., 2019, 6, 192-197.
    https://pubs.rsc.org/en/content/art...

    Photoredox catalysis at copper(II) on chitosan : Application to photolatent CuAAC
    O. Jennah, R. Beniazza, C. Lozach, D. Jardel, F. Molton, C. Duboc, T. Buffeteau, A. El Kadib, D. Lastécouères, M Lahcini,* J.-M. Vincent*
    Adv. Synth. Catal., 2018, 360, 4615-4624.
    https://onlinelibrary.wiley.com/doi...

    Light-mediated iodoperfluoroalkylation of alkenes/alkynes catalyzed by chloride ions : role of halogen bonding
    R. Beniazza, L. Remisse,D. Jardel, D. Lastécouères, J.-M. Vincent*
    Chem. Commun., 2018, 54, 7451-7454.
    https://pubs.rsc.org/en/content/art...

    Fluorous gels of a fluorous alcohol using a low molecular weight anthracene organogelator
    H. Miyajima, M. C. Z. Kasuya, A. Del Guerzo, J.-M Vincent, K. Hatanaka*
    J. Fluor. Chem., 2018, 205, 30-34.
    https://www.sciencedirect.com/scien...

    2D and 3D surface photopatterning via laser-promoted homopolymerization of a perfluorophenyl azide-substituted BODIPY
    G. Raffy,* R. Bofinger, A. Tron, A. Del Guerzo, N. D. McClenaghan, J.-M. Vincent*
    Nanoscale, 2017, 9, 16908-16914.
    https://pubs.rsc.org/en/content/art...

    Light-promoted metal-free cross dehydrogenative couplings on ethers mediated by NFSI : Reactivity and mechanistic studies
    R. Beniazza, B. Abadie, L. Remisse, D. Lastécouères, J.-M. Vincent*
    Chem. Commun., 2017, 53, 12708-12711.
    https://pubs.rsc.org/en/content/art...

    Metal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as source of CF3 and iodine
    R. Beniazza, M. Douarre, D. Lastécouères, J.-M. Vincent*
    Chem. Commun., 2017, 53, 3547-3450.
    http://pubs.rsc.org/en/content/arti...

    Benzophenone vs. copper/benzophenone in light-promoted atom transfer radical additions (ATRAs) : Highly effective iodoperfluoroalkylation of alkenes/alkynes and mechanistic studies
    R. Beniazza, R. Atkinson, C. Absalon, F. Castet, S. A. Denisov, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
    Adv. Synth. Catal., 2016, 358, 2949-2961.
    http://onlinelibrary.wiley.com/doi/...

    A fluorosurfactant and photoreducible CuII-tren click catalyst : surfactant and catalytic properties at liquid/liquid interfaces
    Q. Jochyms, P. Guillot, E. Mignard,* J.-M. Vincent*
    Dalton Trans., 2015, 44, 19700-19707 (Invitation themed issue on “Fluorine”, guest Ed. J. Love)
    http://pubs.rsc.org/en/content/arti...

    Effective ascorbate-free and photolatent click reactions in water using a photoreducible copper(II)-ethylenediamine precatalyst
    R. Beniazza, N. Bayo, F. Molton, C. Duboc, S. Massip, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
    Beilstein J. Org. Chem., 2015, 11, 1950-1959. (Invitation thematic series “Copper catalysis in organic synthesis”, guest Ed. S. R. Chemler)
    https://www.beilstein-journals.org/...

    Copper(I)-photocatalyzed trifluoromethylation of alkenes
    R. Beniazza, F. Molton, C. Duboc, A. Tron, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
    Chem. Commun., 2015, 51, 9571-9574.
    http://pubs.rsc.org/en/content/arti...

    Fluorosurfactants for application in catalysis
    Q. Jochyms, E. Mignard,* J.-M. Vincent*
    J. Fluor. Chem., 2015, 177, 11-18. (Mini-review, invitation special issue “Fluorine in Soft Matter Science”, guest Ed. M.-P. Krafft)
    http://ac.els-cdn.com/S002211391500...

    Sunlight-driven copper-catalyst activation applied to photolatent click chemistry
    R. Beniazza, R. Lambert, L. Harmand, F. Molton, C. Duboc, S. Denisov, G. Jonusauskas, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
    Chem. Eur. J., 2014, 20, 13181-13187. (“Hot Paper”)
    http://onlinelibrary.wiley.com/doi/...

    Organocatalyzed step-growth polymerization through desymmetrization of cyclic anhydrides : Synthesis of chiral polyesters
    A. Martin, F. Robert, D. Taton, H. Cramail,* J.-M. Vincent,* Y. Landais,*
    Chem. Eur. J., 2014, 20, 11946-11953.
    http://onlinelibrary.wiley.com/doi/...

    Polyaldol synthesis by direct organocatalyzed crossed polymerization of bis(ketones) and bis(aldehydes)
    N. Liu, A. Martin, F. Robert, J.-M. Vincent,* Y. Landais,* J. Vignolle, H. Cramail,* D. Taton*
    Macromolecules, 2014, 47, 525-533.
    http://pubs.acs.org/doi/pdf/10.1021...

    One-pot synthesis and PEGylation of hyperbranched polyacetals with a degree of branching of 100%
    N. Liu, J. Vignolle,* J.-M. Vincent, F. Robert, Y. Landais, H. Cramail, D. Taton*
    Macromolecules, 2014, 47, 1532-1542.
    http://pubs.acs.org/doi/pdf/10.1021...

    A Photoreducible Copper(II)-tren Complex of Practical Value : Generation of a Highly Reactive Click Catalyst
    L. Harmand, R. Lambert, L. Scarpantonio, N. D. McClenaghan, D. Lastécouères, J.-M. Vincent*
    Chem. Eur. J., 2013, 19, 16231-16329.
    http://onlinelibrary.wiley.com/doi/...

    Organocatalyzed Aldol Reaction Between Pyridine-2-carbaldehydes and α-Ketoacids. A Straightforward Route Toward Indolizidines and Isotetronic Acids
    V. Liautard, D. Jardel, C. Davies, M. Berlande, T. Buffeteau, D. Cavagnat, F. Robert,* J.-M. Vincent*, Y. Landais*
    Chem. Eur. J., 2013, 19, 14532-14539.
    http://onlinelibrary.wiley.com/doi/...

    Recent advances of fluorous chemistry in material sciences
    J.-M Vincent
    Chem. Commun., 2012, 48, 11382. (“Feature Article”)
    http://pubs.rsc.org/is/content/arti...

    Copper catalyst activation driven by photoinduced electron transfer : A prototype photolatent click catalyst
    L. Harmand, S. Cadet, B. Kauffmann, L. Scarpantino, P. Batat, G. Jonusauskas, D. Lastécouères, J.-M. Vincent*
    Angew. Chem. Int. Ed., 2012, 51, 7137. (“Very Important Paper”)
    http://onlinelibrary.wiley.com/doi/...

    Huisgen click cycloaddition from a copper(II)-tren precatalyst without external sacrificial reductant
    L. Harmand, M.-H. Lescure, N. Candelon, M. Duttine, D. Lastécouères, J.-M. Vincent*
    Tetrahedron Lett., 2012, 53, 1417.
    http://ac.els-cdn.com/S004040391200...

    Fluorous catalysis : From the origin to recent advances
    J.-M. Vincent
    Top. Curr. Chem, 2012, 308, 153.
    http://download.springer.com/static...

    A fluorous copper(II)-carboxylate complex which magnetically and reversibly responds to humidity in the solid state
    A. Motreff , R. Correa da Costa , H. Allouchi , M. Duttine , C. Mathonière , C. Duboc , J.-M. Vincent,*
    J. Fluor. Chem., 2012, 134, 49. (Invitation numéro spécial “Chimie du fluor en France”).
    http://ac.els-cdn.com/S002211391100...

    Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)3]2+ driven by supramolecular heteromeric fluorous carboxylate-carboxylic acid H-bond interaction
    R. Corrêa da Costa, T. Buffeteau, A. Del Guerzo, N. McClenaghan, J.-M. Vincent*
    Chem. Commun., 2011, 47, 8250.
    http://pubs.rsc.org/en/content/arti...

    Self-adaptive hydrophilic and coordinating Teflon surfaces through a straightforward physisorption process
    A. Motreff, C. Belin, R. Correa da Costa, M. El Bakkari, J.-M. Vincent*
    Chem. Commun. , 2010, 46, 6261. (“hot article”).
    http://pubs.rsc.org/en/content/arti...

    Chemisorption of fluorous copper(II)-carboxylates complexes on SiO2 surfaces : Versatile binding layers applied to the preparation of porphyrin monolayers
    A. Motreff, G. Raffy, A. Del Guerzo, C. Belin, M. Dussauze, V. Rodriguez, J.-M. Vincent*
    Chem. Commun., 2010, 46, 2617. _http://pubs.rsc.org/en/content/arti...

    A triblock fluorous surfactant as a specific gelator for perfluorocarbons
    J. Gan, M. El Bakkari, C. Belin, C. Margottin, P. Godard, J.-L. Pozzo,* J.-M. Vincent*
    Chem. Commun., 2009, 5133.
    http://pubs.rsc.org/En/content/arti...

    Dramatic solid-state humidity-induced modification of the magnetic coupling in a dimeric fluorous copper(II)-carboxylate complex
    A Motreff, R. Correa da Costa, H. Allouchi, M. Duttine, C. Mathonière, C. Duboc, J.-M. Vincent*
    Inorg. Chem., 2009, 48, 5623.
    http://pubs.acs.org/doi/pdf/10.1021...

    Noncovalent associations in fluorous fluids (mini-revue)
    J.-M. Vincent
    J. Fluor. Chem. 2008, 129, 903. (Invitation pour un numéro spécial en l’honneur de D. P. Curran).
    http://ac.els-cdn.com/S002211390800...

    A highly active and reusable copper(I)-tren catalyst for the "click" 1,3-dipolar cycloaddition of azides and alkynes
    N. Candelon, D. Lastécouères, A. Khadri Diallo, J. Ruiz Aranzaes, D. Astruc, J.-M. Vincent*
    Chem. Commun., 2008, 741.
    http://pubs.rsc.org/en/content/arti...

    A Copper(II)-Based Multiphasic Fluorous Colorimetric Ethanol Assay
    M. El Bakkari, R. Luguya, R. Correa da Costa, J.-M. Vincent
    New. J. Chem., 2008, 32, 193. ("hot article" avec commentaire éditorial et couverture).
    http://pubs.rsc.org/en/content/arti...

    A concise organocatalytic and enantioselective synthesis of isotetronic acids
    J.-M. Vincent*, C. Margottin, M. Berlande, D. Cavagnat, T. Buffeteau, Y. Landais*
    Chem. Commun., 2007, 4782.
    http://pubs.rsc.org/en/content/arti...

    Benzoimidazole-pyrrolidine/H+ (BIP/H+), a highly reactive organocatalyst for asymmetric processes
    E. Lacoste, E. Vaicque, M. Berlande, I. Pianet, J.-M. Vincent,* Y. Landais*
    Eur. J. Org. Chem., 2007, 167. (Top 10 most-accessed article of the month).
    http://onlinelibrary.wiley.com/doi/...

    Reversible fluorous phase-switching of pyridyl-tagged porphyrins : Application to the sensing of histamine in water
    J. Fluor. Chem., 2006, 127, 4-5, 558. (Invitation numéro spécial : Current Frontiers of fluoroorganic chemistry and recent advances in fluorous chemistry, Eds : D. P. Curran, K. Mikami, V. A. Soloshonok).
    http://ac.els-cdn.com/S002211390500...

    Fluorocarbon soluble copper(II) carboxylate complexes with non-fluorinated nitrogen ligands as precatalysts for the oxidation of alkenols ans alcohols under fluorous biphasic or thermomorphic modes : Structural and mechanistic aspects
    M. Contel,* P. R. Villuendas, J. Fernandez-Gallardo, P. J. Alonso, J.-M. Vincent,* R. H. Fish*
    Inorg. Chem., 2005, 44, 9771.
    http://pubs.acs.org/doi/pdf/10.1021...

    Benzoimidazole-pyrrolidine (BIP), a highly reactive chiral organocatalyst for aldol process
    E. Lacoste, Y. Landais,* K. Schenk, J.-B. Verlhac, J.-M. Vincent*
    Tetrahedron. Lett., 2004, 45, 8035.
    http://ac.els-cdn.com/S004040390401...

    Fluorous phase-switching of pyridyl-tagged substrates/products
    M. El Bakkari, J.-M. Vincent*
    Org. Lett., 2004, 6, 2765.
    http://pubs.acs.org/doi/pdf/10.1021...

    Closer to the « ideal recoverable catalyst” for atom transfer radical polymerisation using a molecular non-fluorous thermomorphic system
    G. Barré, D. Taton, D. Lastécouères, J.-M. Vincent*
    J. Am. Chem. Soc., 2004, 126, 7764.
    http://pubs.acs.org/doi/pdf/10.1021...

    Isomerization dynamics in homo- and heterochiral atropoisomer copper(I) diimine complexes : A 2D EXSY NMR study
    I. Pianet,* J.-M. Vincent*
    Inorg. Chem., 2004, 43, 2947.
    http://pubs.acs.org/doi/pdf/10.1021...

    The pyridyl-tag strategy applied to the hydrocarbon/perfluorocarbon phase-switching of a porphyrin and a fullerene
    M. El Bakkari, N. McClenaghan, J.-M. Vincent*
    J. Am. Chem. Soc., 2002, 124, 12942. http://pubs.acs.org/doi/pdf/10.1021...

Actualités

Publication d’un article VIP dans Angewandte Chemie - Collab. Groupes ORGA-SQ /THEO (Juin.2021)
14 juin

Une synthèse bioinspirée et efficace d’une substance naturelle (...)


Mireille Blanchard Desce – Groupe IPM : article accepté dans la revue Advanced Materials
4 mai

Les résultats à la fois impressionnants et inattendus sont issus (...)


Prix d’instrumentation de la division de chimie physique 2020
8 avril

Lauréats : D. Talaga (Ingénieur de recherche CNRS) et S. Bonhommeau (...)