Mr DEFFIEUX Denis

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Téléphone 05 40 00 30 12
Statut Permanent
Poste Enseignant-chercheur
Batiment A12
Etage RDC Ouest

Publications

Larrieu, R., Cornu, A., Pouységu, L., Deffieux, D., Quideau, S. (). Total Synthesis of (−)-Vescalagin, the Iconic Member of the C-Glucosidic Ellagitannin Family. In Chemistry A European Journal (Vol. 31, Issue 34, p. e202501159). https://doi.org/10.1002/chem.202501159
Larrieu, R., Richieu, A., Cornu, A., Daugey, N., Pouységu, L., Deffieux, D., Quideau, S. (). Copper(II)-Amine Complex-Mediated Intramolecular Coupling of Gallates: A Bioinspired Solution to the Atroposelective Synthesis of Ellagitannins. In Angewandte Chemie International Edition (Vol. 63, Issue 52, p. e202412036). https://doi.org/10.1002/anie.202412036
Sciacca, C., Cardullo, N., Pulvirenti, L., Travagliante, G., D'Urso, A., D'Agata, R., Peri, E., Cancemi, P., Cornu, A., Deffieux, D., Pouységu, L., Quideau, S., Muccilli, V. (). Synthesis of obovatol and related neolignan analogues as α-glucosidase and α-amylase inhibitors. In Bioorganic Chemistry (Vol. 147, p. 107392). https://doi.org/10.1016/j.bioorg.2024.107392
Kempf, K., Capello, Y., Melhem, R., Lescoat, C., Kempf, O., Cornu, A., Fremaux, I., Chaignepain, S., Groppi, A., Nikolski, M., Deffieux, D., Génot, E., Quideau, S. (). Systemic Convergent Multitarget Interactions of Plant Polyphenols Revealed by Affinity-Based Protein Profiling of Bone Cells Using C-Glucosidic Vescal(ag)in-Bearing Chemoproteomic Probes. In ACS Chemical Biology (Vol. 18, Issue 12, p. 2495-2505). https://doi.org/10.1021/acschembio.3c00440
Kempf, K., Kempf, O., Capello, Y., Molitor, C., Lescoat, C., Melhem, R., Chaignepain, S., Génot, E., Groppi, A., Nikolski, M., Halbwirth, H., Deffieux, D., Quideau, S. (). Synthesis of Flavonol-Bearing Probes for Chemoproteomic and Bioinformatic Analyses of Asteraceae Petals in Search of Novel Flavonoid Enzymes. In International Journal of Molecular Sciences (Vol. 24, Issue 11, p. 9724). https://doi.org/10.3390/ijms24119724
Chacón-Morales, P.A., Amaro-Luis, J.M., Rojas Fermín, L.B., Jacquet, R., Deffieux, D., Pouységu, L., Quideau, S. (). Preparation of a ε-caprolactonic diterpenoid derivate by unexpected oxidative cleavage/lactonization of 2-oxoaustroeupatol. In Natural Products and Bioprospecting (Vol. 12, Issue 1, p. 20). https://doi.org/10.1007/s13659-022-00343-2
Gutiérrez, J.E., Fernandez-Moreira, E., Rodríguez, M.A., Mijares, M.R., De Sanctis, J.B., Gurská, S., Džubák, P., Hajdůch, M., Bruno-Colmenarez, J., Rojas, L., Deffieux, D., Pouységu, L., Quideau, S., Charris, J., Ramírez, H. (). Novel 7-Chloro-(4-thioalkylquinoline) Derivatives: Synthesis and Antiproliferative Activity through Inducing Apoptosis and DNA/RNA Damage. In Pharmaceuticals (Vol. 15, Issue 10, p. 1234). https://doi.org/10.3390/ph15101234
Peixoto, P.A., El Assal, M., Chataigner, I., Castet, F., Cornu, A., Coffinier, R., Bosset, C., Deffieux, D., Pouységu, L., Quideau, S. (). Bispericyclic Diels–Alder Dimerization of ortho-Quinols in Natural Product (Bio)Synthesis: Bioinspired Chemical 6-Step Synthesis of (+)-Maytenone. In Angewandte Chemie International Edition (Vol. 60, Issue 27, p. 14967-14974). https://doi.org/10.1002/anie.202103410
Delannoy López, D.M., Tran, D.T., Viault, G., Dairi, S., Peixoto, P.A., Capello, Y., Minder, L., Pouységu, L., Génot, E., Di Primo, C., Deffieux, D., Quideau, S. (). Real-Time Analysis of Polyphenol–Protein Interactions by Surface Plasmon Resonance Using Surface-Bound Polyphenols. In Chemistry A European Journal (Vol. 27, Issue 17, p. 5498-5508). https://doi.org/10.1002/chem.202005187
Dumont, U., Sanchez, S., Olivier, B., Chateil, J.F., Deffieux, D., Quideau, S., Pellerin, L., Beauvieux, M.C., Bouzier-Sore, A.K., Roumes, H. (). Maternal alcoholism and neonatal hypoxia-ischemia: Neuroprotection by stilbenoid polyphenols. In Brain Research (Vol. 1738, p. 146798). https://doi.org/10.1016/j.brainres.2020.146798
Cardullo, N., Muccilli, V., Pulvirenti, L., Cornu, A., Pouységu, L., Deffieux, D., Quideau, S., Tringali, C. (). C-glucosidic ellagitannins and galloylated glucoses as potential functional food ingredients with anti-diabetic properties: a study of α-glucosidase and α-amylase inhibition. In Food Chemistry (Vol. 313, p. 126099). https://doi.org/10.1016/j.foodchem.2019.126099
Rodríguez, M., Gutiérrez, J., Domínguez, J., Peixoto, P.A., Fernández, A., Rodríguez, N., Deffieux, D., Rojas, L., Quideau, S., Pouységu, L., Charris, J. (). Synthesis and leishmanicidal evaluation of sulfanyl- and sulfonyl-tethered functionalized benzoate derivatives featuring a nitroimidazole moiety. In Archiv Der Pharmazie (Vol. 353, Issue 5, p. e2000002). https://doi.org/10.1002/ardp.202000002
Antien, K., Lacambra, A., Cossío, F.P., Massip, S., Deffieux, D., Pouységu, L., Peixoto, P.A., Quideau, S. (). Bio-inspired Total Synthesis of Twelve Securinega Alkaloids: Structural Reassignments of (+)-Virosine B and (−)-Episecurinol A. In Chemistry A European Journal (Vol. 25, Issue 49, p. 11574-11580). https://doi.org/10.1002/chem.201903122
Soares, S., Brandaõ, E., Garciá-Estevez, I., Fonseca, F., Guerreiro, C., Ferreira-Da-Silva, F., Mateus, N., Deffieux, D., Quideau, S., De Freitas, V. (). Interaction between Ellagitannins and Salivary Proline-Rich Proteins. In Journal of Agricultural and Food Chemistry (Vol. 67, Issue 34, p. 9579-9590). https://doi.org/10.1021/acs.jafc.9b02574
Chacon-Morales, P.A., Amaro-Luis, J.M., Rojas Fermin, L.B., Rios Tesch, N.N., Lucena Escalona, M.E., Rodriguez Pena, M.A., Peixoto, P.A., Jacquet, R., Deffieux, D., Pouysegu, L., Quideau, S. (). Hemisynthesis and Bactericidal Activity of Several Substituted Benzoic Acid Esters of 13(S)-Labdan-8α,15-Diol, a Diterpene from Oxylobus glanduliferus. In Chemistry of Natural Compounds (Vol. 55, Issue 4, p. 677-684). https://doi.org/10.1007/s10600-019-02777-6
Antien, K., Pouységu, L., Deffieux, D., Massip, S., Peixoto, P.A., Quideau, S. (). Synthesis of [7]Helicene Enantiomers and Exploratory Study of Their Conversion into Helically Chiral Iodoarenes and Iodanes. In Chemistry A European Journal (Vol. 25, Issue 11, p. 2852-2858). https://doi.org/10.1002/chem.201805761
Chacón-Morales, P.A., Amaro-Luis, J.M., Beltrán Rojas Fermín, L., Peixoto, P.A., Deffieux, D., Pouységu, L., Quideau, S. (). Preparation and bactericidal activity of oxidation derivatives of austroeupatol, an ent-nor-furano diterpenoid of the labdane series from Austroeupatorium inulifolium. In Phytochemistry Letters (Vol. 29, p. 47-52). https://doi.org/10.1016/j.phytol.2018.11.007
Petit, E., Jacquet, R., Pouységu, L., Deffieux, D., Quideau, S. (). Reactivity of wine polyphenols under oxidation conditions: Hemisynthesis of adducts between grape catechins or oak ellagitannins and odoriferous thiols. In Tetrahedron (Vol. 75, Issue 5, p. 551-560). https://doi.org/10.1016/j.tet.2018.11.071
Vilhelmova-Ilieva, N., Jacquet, R., Deffieux, D., Pouységu, L., Sylla, T., Chassaing, S., Nikolova, I., Quideau, S., Galabov, A.S. (). Anti-Herpes Simplex Virus Type 1 Activity of Specially Selected Groups of Tannins. In Drug Research (Vol. 69, Issue 7, p. 374-381). https://doi.org/10.1055/a-0640-2557
Bowers, J.J., Gunawardena, H.P., Cornu, A., Narvekar, A.S., Richieu, A., Deffieux, D., Quideau, S., Tharayil, N. (). Rapid Screening of Ellagitannins in Natural Sources via Targeted Reporter Ion Triggered Tandem Mass Spectrometry. In Scientific Reports (Vol. 8, Issue 1, p. 10399). https://doi.org/10.1038/s41598-018-27708-3
Georgess, D., Spuul, P., Le Clainche, C., Le Nihouannen, D., Fremaux, I., Dakhli, T., Delannoy López, D.M., Deffieux, D., Jurdic, P., Quideau, S., Génot, E. (). Anti-osteoclastic effects of C-glucosidic ellagitannins mediated by actin perturbation. In European Journal of Cell Biology (Vol. 97, Issue 8, p. 533-545). https://doi.org/10.1016/j.ejcb.2018.09.003
El Assal, M., Peixoto, P.A., Coffinier, R., Garnier, T., Deffieux, D., Miqueu, K., Sotiropoulos, J.M., Pouységu, L., Quideau, S. (). Synthesis of Scyphostatin Analogues through Hypervalent Iodine-Mediated Phenol Dearomatization. In Journal of Organic Chemistry (Vol. 82, Issue 22, p. 11816-11828). https://doi.org/10.1021/acs.joc.7b02366
Richieu, A., Peixoto, P.A., Pouységu, L., Deffieux, D., Quideau, S. (). Bioinspired Total Synthesis of (−)-Vescalin: A Nonahydroxytriphenoylated C-Glucosidic Ellagitannin. In Angewandte Chemie International Edition (Vol. 56, Issue 44, p. 13833-13837). https://doi.org/10.1002/anie.201707613
Quideau, S., Pouységu, L., Peixoto, P.A., Deffieux, D. (). Phenol dearomatization with hypervalent iodine reagents. In Topics in Current Chemistry (Vol. 373, p. 25-74). https://doi.org/10.1007/128_2015_665
Watrelot, A.A., Tran, D.T., Buffeteau, T., Deffieux, D., Le Bourvellec, C., Quideau, S., Renard, C.M.G.C. (). Immobilization of flavan-3-ols onto sensor chips to study their interactions with proteins and pectins by SPR. In Applied Surface Science (Vol. 371, p. 512-518). https://doi.org/10.1016/j.apsusc.2016.03.002
Sylla, T., Pouységu, L., Dacosta, G., Deffieux, D., Monti, J.P., Quideau, S. (). Gallotannins and Tannic Acid: First Chemical Syntheses and in Vitro Inhibitory Activity on Alzheimer's Amyloid β-Peptide Aggregation. In Angewandte Chemie International Edition (Vol. 54, Issue 28, p. 8217-8221). https://doi.org/10.1002/anie.201411606
Sosic, A., Cappellini, M., Sinigaglia, L., Jacquet, R., Deffieux, D., Fabris, D., Quideau, S., Gatto, B. (). Polyphenolic C-glucosidic ellagitannins present in oak-aged wine inhibit HIV-1 nucleocapsid protein. In Tetrahedron (Vol. 71, Issue 20, p. 3020-3026). https://doi.org/10.1016/j.tet.2015.01.035
Petit, E., Jacquet, R., Pouységu, L., Deffieux, D., Quideau, S. (). About the impact of oak ellagitannins on wine odoriferous thiols under acidic and oxidation conditions. In Tetrahedron (Vol. 71, Issue 20, p. 2991-2998). https://doi.org/10.1016/j.tet.2015.02.036
Carrié, H., Tran, D.T., Rousseau, S., Chaignepain, S., Schmitter, J.M., Deffieux, D., Quideau, S. (). New affinity-based probes for capturing flavonoid-binding proteins. In Chemical Communications (Vol. 50, Issue 67, p. 9387-9389). https://doi.org/10.1039/c4cc04557b
Deffieux, D., Gossart, P., Quideau, S. (). Facile and sustainable synthesis of the natural antioxidant hydroxytyrosol. In Tetrahedron Letters (Vol. 55, Issue 15, p. 2455-2458). https://doi.org/10.1016/j.tetlet.2014.02.134
Quideau, S., Deffieux, D., Pouységu, L. (). Oxidative Coupling of Phenols and Phenol Ethers. In Comprehensive Organic Synthesis Second Edition (Vol. 3, p. 656-740). https://doi.org/10.1016/B978-0-08-097742-3.00318-9
Douat, C., Berni, E., Jacquet, R., Pouységu, L., Deffieux, D., Quideau, S. (). Protecting-group-free solid-phase anchoring of polyphenolic C-glucosidic ellagitannins and synthesis of 1-alkylamino-vescalagin derivatives. In European Journal of Organic Chemistry (Vol. 2014, Issue 23, p. 4963-4972). https://doi.org/10.1002/ejoc.201402444
Petit, E., Lefeuvre, D., Jacquet, R., Pouységu, L., Deffieux, D., Quideau, S. (). Remarkable biomimetic chemoselective aerobic oxidation of flavano-ellagitannins found in oak-aged wine. In Angewandte Chemie International Edition (Vol. 52, Issue 44, p. 11530-11533). https://doi.org/10.1002/anie.201305839
Jourdes, M., Pouységu, L., Deffieux, D., Teissedre, P.L., Quideau, S. (). Hydrolyzable tannins: Gallotannins and ellagitannins. In Natural Products Phytochemistry Botany and Metabolism of Alkaloids Phenolics and Terpenes (p. 1975-2010). https://doi.org/10.1007/978-3-642-22144-6_65
Malik, G., Natangelo, A., Charris, J., Pouységu, L., Manfredini, S., Cavagnat, D., Buffeteau, T., Deffieux, D., Quideau, S. (). Synthetic studies toward c-glucosidic ellagitannins: A biomimetic total synthesis of 5-O-desgalloylepipunicacortein A. In Chemistry A European Journal (Vol. 18, Issue 29, p. 9063-9074). https://doi.org/10.1002/chem.201200517
Quideau, S., Deffieux, D., Pouységu, L. (). Resveratrol still has something to say about aging!. In Angewandte Chemie International Edition (Vol. 51, Issue 28, p. 6824-6826). https://doi.org/10.1002/anie.201203059
Auzanneau, C., Montaudon, D., Jacquet, R., Puyo, S., Pouységu, L., Deffieux, D., Elkaoukabi-Chaibi, A., De Giorgi, F., Ichas, F., Quideau, S., Pourquier, P. (). The polyphenolic ellagitannin vescalagin acts as a preferential catalytic inhibitor of the α isoform of human DNA topoisomerase II. In Molecular Pharmacology (Vol. 82, Issue 1, p. 134-141). https://doi.org/10.1124/mol.111.077537
Bernini, R., Fabrizi, G., Pouységu, L., Deffieux, D., Quideau, S. (). Synthesis of Biologically Active Catecholic Compounds via ortho-Selective Oxygenation of Phenolic Compounds Using Hypervalent Iodine(V) Reagents. In Current Organic Synthesis (Vol. 9, Issue 5, p. 650-669). https://doi.org/10.2174/157017912803251792
Deffieux, D., Natangelo, A., Malik, G., Pouységu, L., Charris, J., Quideau, S. (). First and biomimetic total synthesis of a member of the C-glucosidic subclass of ellagitannins, 5-O-desgalloylepipunicacortein A. In Chemical Communications (Vol. 47, Issue 5, p. 1628-1630). https://doi.org/10.1039/c0cc04007j
Quideau, S., Deffieux, D., Douat-Casassus, C., Pouységu, L. (). Plant polyphenols: Chemical properties, biological activities, and synthesis. In Angewandte Chemie International Edition (Vol. 50, Issue 3, p. 586-621). https://doi.org/10.1002/anie.201000044
Pouységu, L., Deffieux, D., Malik, G., Natangelo, A., Quideau, S. (). Synthesis of ellagitannin natural products. In Natural Product Reports (Vol. 28, Issue 5, p. 853-874). https://doi.org/10.1039/c0np00058b
Chalumeau, C., Deffieux, D., Chaignepain, S., Quideau, S. (). Development of an Affinity-Based Proteomic Strategy for the Elucidation of Proanthocyanidin Biosynthesis. In Chembiochem (Vol. 12, Issue 8, p. 1193-1197). https://doi.org/10.1002/cbic.201100044
Pouységu, L., Sylla, T., Garnier, T., Rojas, L.B., Charris, J., Deffieux, D., Quideau, S. (). Hypervalent iodine-mediated oxygenative phenol dearomatization reactions. In Tetrahedron (Vol. 66, Issue 31, p. 5908-5917). https://doi.org/10.1016/j.tet.2010.05.078
Pouységu, L., Deffieux, D., Quideau, S. (). Hypervalent iodine-mediated phenol dearomatization in natural product synthesis. In Tetrahedron (Vol. 66, Issue 13, p. 2235-2261). https://doi.org/10.1016/j.tet.2009.12.046
Deffieux, D., Gaudrel-Grosay, S., Grelard, A., Chalumea, C., Quideau, S. (). Stable solid-supported leucoanthocyanidin variants for flavanoid biosynthesis elucidation. In Tetrahedron Letters (Vol. 50, Issue 47, p. 6567-6571). https://doi.org/10.1016/j.tetlet.2009.09.045
Quideau, S., Pouységu, L., Deffïeux, D. (). Oxidative dearomatization of phenols: Why, how and what for?. In Synlett (Issue 4, p. 467-495). https://doi.org/10.1055/s-2008-1032094
Gagnepain, J., Méreau, R., Dejugnac, D., Léger, J.M., Castet, F., Deffieux, D., Pouységu, L., Quideau, S. (). Regio- and stereoselectivities in Diels-Alder cyclodimerizations of orthoquinonoid cyclohexa-2,4-dienones. In Tetrahedron (Vol. 63, Issue 28, p. 6493-6505). https://doi.org/10.1016/j.tet.2007.03.035
Deffieux, D., Fabre, I., Titz, A., Léger, J.M., Quideau, S. (). Electrochemical synthesis of dimerizing and nondimerizing orthoquinone monoketals. In Journal of Organic Chemistry (Vol. 69, Issue 25, p. 8731-8738). https://doi.org/10.1021/jo048677i
Quideau, S., Fabre, I., Deffieux, D. (). First asymmetric synthesis of orthoquinone monoketal enantiomers via anodic oxidation. In Organic Letters (Vol. 6, Issue 24, p. 4571-4573). https://doi.org/10.1021/ol048030k
Quideau, S., Pouységu, L., Deffieux, D. (). Chemical and electrochemical oxidative activation of arenol derivatives for carbon-carbon bond formation. In Current Organic Chemistry (Vol. 8, Issue 2, p. 113-148). https://doi.org/10.2174/1385272043486016
Deffieux, D., Fabre, I., Courseille, C., Quideau, S. (). Electrochemically-induced spirolactonization of α-(methoxyphenoxy)alkanoic acids into quinone ketals. In Journal of Organic Chemistry (Vol. 67, Issue 13, p. 4458-4465). https://doi.org/10.1021/jo020023r
Buchholz, H.A., Prakash, G.K.S., Deffieux, D., Olah, G.A. (). Electrochemical preparation of tris(tert-butyldimethylsilyl)cyclopropene and its hydride abstraction to tris(tert-butyldimethylsilyl)cyclopropenium tetrafluoroborate. In Proceedings of the National Academy of Sciences of the United States of America (Vol. 96, Issue 18, p. 10003-10005). https://doi.org/10.1073/pnas.96.18.10003
Pouységu, L., Nobert, P., Deffieux, D., De Jéso, B., Lartigue, J.C., Pétraud, M., Ratier, M. (). Investigations on computed 13C NMR one-dimensional non-refocused INEPT experiments for structural determinations in O-methylated glycosides. In Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy (Vol. 55, Issue 12, p. 2383-2391). https://doi.org/10.1016/S1386-1425(99)00025-6
Yudin, A.K., Prakash, G.K.S., Deffieux, D., Bradley, M., Bau, R., Olah, G.A. (). Preparation of and fluoroalkylation with (chlorodifluoromethyl)trimethylsilane, difluorobis(trimethylsilyl)methane, and 1,1,2,2-tetrafluoro-1,2-bis(trimethylsilyl)ethane. In Journal of the American Chemical Society (Vol. 119, Issue 7, p. 1572-1581). https://doi.org/10.1021/ja962990n
Olah, G.A., Batamack, P., Deffieux, D., Török, B., Wang, Q., Molnár, A., Prakash, G.K.S. (). Acidity dependence of the trifluoromethanesulfonic acid catalyzed isobutane-isobutylene alkylation modified with trifluoroacetic acid or water. In Applied Catalysis A General (Vol. 146, Issue 1, p. 107-117). https://doi.org/10.1016/0926-860X(96)00045-2
Deffieux, D., Bonafoux, D., Bordeau, M., Biran, C., Dunoguès, J. (). Selective electrochemical mono- and polysilylation of halothiophenes. In Organometallics (Vol. 15, Issue 8, p. 2041-2046). https://doi.org/10.1021/om950605h
Prakash, G.K.S., Yudin, A.K., Deffieux, D., Olah, G.A. (). Facile Preparation of (Trifluoromethyl)tributyltin and Transtrifluoromethylation of Disilyl Sulfides to the Corresponding Trifluoromethylsilanes. In Synlett (Vol. 1996, Issue 2, p. 151-153). https://doi.org/10.1055/s-1996-5355
Biran, C., Bordeau, M., Bonafoux, D., Deffieux, D., Duprat, C., Jouikov, V., Léger-Lambert, M.P., Moreau, C., Serein-Spirau, F. (). L'électrosynthése à anode consommable: Quel apport pour la chimie organique du silicium ?. In Journal De Chimie Physique Et De Physico Chimie Biologique (Vol. 93, Issue 4, p. 591-600). https://doi.org/10.1051/jcp/1996930591
Surya Prakash, G.K., Deffieux, D., Yudin, A.K., Olah, G.A. (). Convenient and Safe Electrochemical Synthesis of (Trifluoromethyl)trimethylsilane 1a. In Synlett (Vol. 1994, Issue 12, p. 1057-1058). https://doi.org/10.1055/s-1994-34986
Prakash, G.K.S., Buchholz, H.A., Deffieux, D., Olah, G.A. (). Electrochemical Synthesis of Hexakis(trimethylsilyl)-3,3′-bicyclopropenyl. In Journal of Organic Chemistry (Vol. 59, Issue 24, p. 7532-7533). https://doi.org/10.1021/jo00103a062
Surya Prakash, G.K., Buchholz, H.A., Deffieux, D., Olah, G.A. (). Selective Electrochemical Trimethylsilylation of Tetrachlorocyclopropene to 1-(Trimethylsilyl)-trichlorocyclopropene, a New Cyclopropene Building Block 1. In Synlett (Vol. 1994, Issue 10, p. 819-820). https://doi.org/10.1055/s-1994-23015
Grelier, S., Constantieux, T., Deffieux, D., Bordeau, M., Dunoguès, J., Picard, J.P., Palomo, C., Aizpurua, J.M. (). Reductive Electrochemical Silylation of Unsaturated Nitrogen Functionalities: A Simple and Efficient Synthesis of Precursors of Bis(trimethylsilyl)methylamine. In Organometallics (Vol. 13, Issue 9, p. 3711-3714). https://doi.org/10.1021/om00021a051
Deffieux, D., Bordeau, M., Biran, C., Dunoguès, J. (). Electrochemical Trimethylsilylation of o-Dichlorobenzene: A Selective Route to Silylated Cyclo-C6 Synthons. In Organometallics (Vol. 13, Issue 6, p. 2415-2422). https://doi.org/10.1021/om00018a039