Image

Téléphone
05 40 00 28 29
Groupe de recherche
Catalysis, Synthesis and Health
Statut
Permanent
Poste
Enseignant-chercheur
Batiment
A12
Etage
1° Ouest
Curriculum Vitae
depuis 2015 : Professeur des Universités, Université de Bordeaux
2005-2015 : Maître de Conférences, Ecole Nationale Supérieure de Chimie de Paris – Chimie ParisTech
2004-2005 : Stagiaire postdoctoral, Université de Groningen, Pays-Bas. Prof. Ben Feringa, Prof. Adri Minnaard, Prof. Hans de Vries.
2002-2004 : Stagiaire postdoctoral, ETH Zürich, Suisse. Prof. Antonio Togni.
1999-2002 : Doctorat de l’Ecole Polytechnique, Palaiseau. Prof. François Mathey.
Contact
patrick.toullec@u-bordeaux.fr
ISM, UMR-CNRS 5255, Groupe Nanosciences Moléculaires et Catalyse Université de Bordeaux, Batiment A12 351, cours de la libération 33405 Talence Cedex
Publications
Brønsted Acid-Catalyzed Enantioselective and Para-Selective Addition of Phenols to 1-Alkynylnaphth-2-Ols. In Advanced Synthesis and Catalysis. https://doi.org/10.1002/adsc.202401457
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Benzisoselenazoles as Selenophenolate Anion Surrogates for the Formation of Carbon-Selenium Bonds via the Selena-Kemp Reaction. In Journal of Organic Chemistry (Vol. 89, Issue 15, p. 10462-10466). https://doi.org/10.1021/acs.joc.4c00581
().
Asymmetric Allenylation of Alkynes mediated by Chiral Organoselenated Reagents under Oxidative Conditions. In Angewandte Chemie - International Edition (Vol. 62, Issue 42, p. e202310436). https://doi.org/10.1002/anie.202310436
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Bronsted Acid Catalyzed Carbocyclizations Involving Electrophilic Activation of Alkynes. In Synthesis (Germany) (Vol. 54, Issue 24, p. 5360-5384). https://doi.org/10.1055/a-1927-8439
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Alkylation of the α-amino C-H bonds of anilines photocatalyzed by a DMEDA-Cu-benzophenone complex: reaction scope and mechanistic studies. In Organic and Biomolecular Chemistry (Vol. 19, Issue 26, p. 5800-5805). https://doi.org/10.1039/d1ob00960e
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Brønsted Acid-Catalyzed Enantioselective Cycloisomerization of Arylalkynes. In Chemistry - A European Journal (Vol. 26, Issue 69, p. 16266-16271). https://doi.org/10.1002/chem.202003783
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Dual Benzophenone/Copper-Photocatalyzed Giese-Type Alkylation of C(sp3)−H Bonds. In Chemistry - A European Journal (Vol. 25, Issue 70, p. 16120-16127). https://doi.org/10.1002/chem.201904111
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Brønsted Acid-Catalyzed Carbocyclization of 2-Alkynyl Biaryls. In Advanced Synthesis and Catalysis (Vol. 361, Issue 9, p. 2025-2030). https://doi.org/10.1002/adsc.201801526
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Assessing the Activity of Lewis Bases Organocatalysts in Halonium-Induced Carbocyclization Reactions. In Synlett (Vol. 29, Issue 9, p. 1181-1186). https://doi.org/10.1055/s-0036-1591982
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Gold-Catalyzed Polycyclization Toward Natural Products Synthesis. In Israel Journal of Chemistry (Vol. 58, Issue 5, p. 578-585). https://doi.org/10.1002/ijch.201800002
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Iodonium-Induced Cyclization of N -Allenylindoles and N -Allenylpyrroles: An Access to Iododihydropyrido[1,2- a ]indoles and Dihydroindolizines. In Synlett (Vol. 29, Issue 3, p. 310-313). https://doi.org/10.1055/s-0036-1591506
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Synthesis and complexing properties of molecular probes linked with fluorescent phosphane oxide derivatives. In Journal of Photochemistry and Photobiology A: Chemistry (Vol. 318, p. 25-32). https://doi.org/10.1016/j.jphotochem.2015.11.017
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Synthesis of Polysubstituted 2-Iodoindenes via Iodonium-Induced Cyclization of Arylallenes. In Organic Letters (Vol. 18, Issue 4, p. 676-679). https://doi.org/10.1021/acs.orglett.5b03634
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Phase-Transfer-Catalyzed Oxaziridine-Mediated Hydroxylative Phenol and Naphthol Dearomatization. In European Journal of Organic Chemistry (Vol. 2016, Issue 2, p. 260-264). https://doi.org/10.1002/ejoc.201501340
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Carbophilic Cycloisomerization Reactions of Enynesand Domino Processes. In Modern Alkyne Chemistry: Catalytic and Atom-Economic Transformations (Vol. 9783527335053, p. 27-68). https://doi.org/10.1002/9783527677894.ch3
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Silver-catalyzed domino hydroarylation/cycloisomerization reactions of ortho-alkynylbenzaldehydes: An entry to functionalized isochromene derivatives. In Organic Letters (Vol. 16, Issue 17, p. 4570-4573). https://doi.org/10.1021/ol5021256
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Combinatorial approach to chiral tris-ligated carbophilic platinum complexes: Application to asymmetric catalysis. In Chemistry - A European Journal (Vol. 20, Issue 23, p. 7128-7135). https://doi.org/10.1002/chem.201304794
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Ultra-sensitive and selective Hg2+ chemosensors derived from substituted 8-hydroxyquinoline analogues. In New Journal of Chemistry (Vol. 38, Issue 3, p. 1072-1078). https://doi.org/10.1039/c3nj01308a
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Water-soluble Gold(I) and Gold(III) complexes with sulfonated N-heterocyclic carbene ligands: Synthesis, characterization, and application in the catalytic cycloisomerization of γ-alkynoic acids into enol-lactones. In ACS Catalysis (Vol. 3, Issue 12, p. 3086-3098). https://doi.org/10.1021/cs4009144
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Gold-catalyzed C-H oxidative polyacyloxylation reaction of hindered arenes. In Synthesis (Germany) (Vol. 44, Issue 15, p. 2463-2468). https://doi.org/10.1055/s-0032-1316541
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Cycloisomerization versus hydration reactions in aqueous media: A Au(III)-NHC catalyst that makes the difference. In Organic Letters (Vol. 14, Issue 10, p. 2520-2523). https://doi.org/10.1021/ol300811e
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Gold-catalyzed cycloisomerization of functionalized 1,5-enynes - An entry to polycyclic framework. In Synlett (Issue 1, p. 74-79). https://doi.org/10.1055/s-0031-1289867
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Gold-catalyzed oxidative acyloxylation of arenes. In Organic Letters (Vol. 13, Issue 22, p. 6086-6089). https://doi.org/10.1021/ol202577c
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Cycloisomerization of 1,n-enynes via carbophilic activation. In Topics in Current Chemistry (Vol. 302, p. 31-80). https://doi.org/10.1007/128_2010_116
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Asymmetric Au-catalyzed cycloisomerization of 1,6-enynes: An entry to bicyclo[4.1.0]heptene. In Beilstein Journal of Organic Chemistry (Vol. 7, p. 1021-1029). https://doi.org/10.3762/bjoc.7.116
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Asymmetric Au-catalyzed domino cyclization/nucleophile addition reactions of enynes in the presence of water, methanol and electron-rich aromatic derivatives. In Tetrahedron (Vol. 67, Issue 24, p. 4371-4377). https://doi.org/10.1016/j.tet.2011.03.071
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Synthesis, photophysical, and two-photon absorption properties of elongated phosphane oxide and sulfide derivatives. In Chemistry - An Asian Journal (Vol. 6, Issue 4, p. 1080-1091). https://doi.org/10.1002/asia.201000681
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Recent developments in asymmetric catalysis in the presence of Chiral gold complexes. In Synthesis (Issue 10, p. 1501-1514). https://doi.org/10.1055/s-0030-1258465
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Fluorescent phosphane selenide as efficient mercury chemodosimeter. In Organic Letters (Vol. 13, Issue 5, p. 1182-1185). https://doi.org/10.1021/ol200066p
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Novel Pd heterogeneous catalysts for cycloisomerisation of acetylenic carboxylic acids. In Green Chemistry (Vol. 12, Issue 12, p. 2145-2149). https://doi.org/10.1039/c0gc00258e
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Chiral undecagold clusters: Synthesis, characterization and investigation in catalysis. In Dalton Transactions (Vol. 39, Issue 44, p. 10608-10616). https://doi.org/10.1039/c0dt00399a
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Room-temperature metal-free electrophilic 5-endo -selective iodocarbocyclization of 1,5-enynes. In Organic Letters (Vol. 12, Issue 22, p. 5222-5225). https://doi.org/10.1021/ol102257z
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Chiral cationic platinum complexes: New catalysts for the activation of carbon-carbon multiple bonds towards nucleophilic enantioselective attack. In Current Organic Chemistry (Vol. 14, Issue 12, p. 1245-1253). https://doi.org/10.2174/138527210791330431
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Heterogeneous Au and Rh catalysts for cycloisomerization reactions of γacetylenic carboxylic acids. In Pure and Applied Chemistry (Vol. 81, Issue 12, p. 2387-2396). https://doi.org/10.1351/PAC-CON-09-01-01
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Mimicking polyolefin carbocyclization reactions: Gold-Catalyzed intramolecular phenoxycyclization of 1,5-enynes. In Organic Letters (Vol. 11, Issue 13, p. 2888-2891). https://doi.org/10.1021/ol900864n
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Synthesis of polycyclic heterocycles via sequential Au-catalyzed cycloisomerization and Ru-catalyzed metathesis reactions. In Tetrahedron Letters (Vol. 50, Issue 26, p. 3719-3722). https://doi.org/10.1016/j.tetlet.2009.04.001
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Synthesis of functionalized carbo- and heterocycles via gold-catalyzed cycloisomerization reactions of enynes. In Tetrahedron (Vol. 65, Issue 9, p. 1911-1918). https://doi.org/10.1016/j.tet.2008.11.105
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Towards asymmetric Au-catalyzed hydroxy- and alkoxycyclization of 1,6-enynes. In Journal of Organometallic Chemistry (Vol. 694, Issue 4, p. 538-545). https://doi.org/10.1016/j.jorganchem.2008.08.008
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Asymmetric gold-catalyzed hydroarylation/cyclization reactions. In Chemistry - A European Journal (Vol. 15, Issue 6, p. 1319-1323). https://doi.org/10.1002/chem.200802341
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Asymmetric Au(i)-catalyzed synthesis of bicyclo[4.1.0]heptene derivatives via a cycloisomerization process of 1,6-enynes. In Chemical Communications (Issue 45, p. 6988-6990). https://doi.org/10.1039/b913554e
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Heterogeneous gold catalysts for efficient access to functionalized lactones. In Chemistry - A European Journal (Vol. 14, Issue 30, p. 9412-9418). https://doi.org/10.1002/chem.200801327
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Enantioselective platinum-catalyzed tandem hydroarylation- cycloisomerization of 1,6-enynes. In Advanced Synthesis and Catalysis (Vol. 350, Issue 14-15, p. 2401-2408). https://doi.org/10.1002/adsc.200800446
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Cycloisomerization of 1,n-enynes: Challenging metal-catalyzed rearrangements and mechanistic insights. In Angewandte Chemie - International Edition (Vol. 47, Issue 23, p. 4268-4315). https://doi.org/10.1002/anie.200701589
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Au2 O3 as a stable and efficient catalyst for the selective cycloisomerization of γ-acetylenic carboxylic acids to γ-alkylidene-γ-butyrolactones. In Synlett (Issue 5, p. 707-711). https://doi.org/10.1055/s-2008-1032108
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Gold-catalyzed hydroamination/cycloisomerization reaction of 1,6-enynes. In Organic Letters (Vol. 9, Issue 20, p. 4049-4052). https://doi.org/10.1021/ol7017483
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Gold-catalyzed hydroxy- and alkoxycyclization of functionalized enynes. In Synlett (Issue 11, p. 1780-1784). https://doi.org/10.1055/s-2007-982570
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Synthesis of solution-phase phosphoramidite and phosphite ligand libraries and their in situ screening in the rhodium-catalyzed asymmetric addition of arylboronic acids. In Journal of Combinatorial Chemistry (Vol. 9, Issue 3, p. 407-414). https://doi.org/10.1021/cc060161k
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Gold catalysis in organic synthesis: Efficient intramolecular cyclization of γ-acetylenic carboxylic acids to 5-exo-alkylidene-butyrolactones. In Arkivoc (Vol. 2007, Issue 5, p. 67-78). https://doi.org/10.3998/ark.5550190.0008.507
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Room-temperature AuI-catalyzed C-C bond formation through a tandem Friedel-Crafts-type addition/carbocyclization reaction. In Angewandte Chemie - International Edition (Vol. 45, Issue 44, p. 7427-7430). https://doi.org/10.1002/anie.200601980
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Rhodium-catalyzed addition of arylboronic acids to isatins: An entry to diversity in 3-aryl-3-hydroxyoxindoles. In Organic Letters (Vol. 8, Issue 13, p. 2715-2718). https://doi.org/10.1021/ol0608101
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A ligand-library approach to the highly efficient rhodium/phosphoramidite- catalyzed asymmetric arylation of N,N-dimethylsulfamoyl-protected aldimines. In Angewandte Chemie - International Edition (Vol. 45, Issue 17, p. 2789-2791). https://doi.org/10.1002/anie.200504309
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Room temperature Au(I)-catalyzed exo-selective cycloisomerization of acetylenic acids: An entry to functionalized γ-lactones. In Journal of the American Chemical Society (Vol. 128, Issue 10, p. 3112-3113). https://doi.org/10.1021/ja056857j
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Rhodium/phosphoramidite-catalyzed asymmetric arylation of aldehydes with arylboronic acids. In Organic and Biomolecular Chemistry (Vol. 4, Issue 5, p. 773-775). https://doi.org/10.1039/b518311a
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Relative electrophilic fluorinating power as assayed by competitive catalytic halogenation reactions. In Helvetica Chimica Acta (Vol. 87, Issue 10, p. 2706-2711). https://doi.org/10.1002/hlca.200490240
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Expanding the scope of asymmetric electrophilic atom-transfer reactions: Titanium- and ruthenium-catalyzed hydroxylation of β-ketoesters. In Proceedings of the National Academy of Sciences of the United States of America (Vol. 101, Issue 16, p. 5810-5814). https://doi.org/10.1073/pnas.0307716101
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Stereoselective preparation of Z-trisubstituted alkylidene cyclic carbonates via palladium-catalyzed carbon - carbon bond formation. In Tetrahedron Letters (Vol. 41, Issue 29, p. 5527-5531). https://doi.org/10.1016/S0040-4039(00)00889-3
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