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Téléphone
05 40 00 27 52
Groupe de recherche
Nano-structures Organiques
Statut
Permanent
Poste
Enseignant-chercheur
Batiment
A12
Etage
1° Est
RESEARCH TOPICS
• Photochromisme
• Auto-assemblages Photomodulables
• Photocatalyse Hétérogène
• Nanostructures Organique
• Ingénierie Moléculaire
PROFESSIONNAL EXPERIENCE
• 2017 Professeur Classe Exceptionnelle PRCE2
• 2002 Professeur des Universités
• 1999 HDR
• 1994 Maître de Conférences
• Biographical Sketch
- B.S. degree (1987) from Paris VI University.
- National School of Chemistry of Paris (ENSCP) in 1989.
- M.S. degree from Aix-Marseille II University (1990).
- Ph.D. (1993) in Organic and Physical Chemistry from Université de la Méditerranée (Marseilles). His studies were focussed on T-type photochromes such as chromenes and naphthooxazines.
Essilor International-PPG Industries offered him a grant for an industrial post-doctoral stay on tunable ophthalmic lenses.
He moved to Bordeaux University as a research associate and was promoted to Associate Professor at the Laboratory of Organic and Organometallic Chemistry in 1998.
In 2002 he was appointed to Professor in Supramolecular Chemistry, Bordeaux University and developped photoswitchable NLOphores and gelators. He recently developed new photo responsive heterogeneous catalysts.
Publications
(). Mechanistic insights into the thermal ground-state recovery of salicylidene aniline photoswitches. In Dyes and Pigments (Vol. 247, p. 113472). https://doi.org/10.1016/j.dyepig.2025.113472
(). Cu(I)-Glutathione Assembly Supported on ZIF-8 as Robust and Efficient Catalyst for Mild CO2 Conversions. In Angewandte Chemie International Edition (Vol. 63, Issue 37, p. e202407430). https://doi.org/10.1002/anie.202407430
(). Hydration of Unsymmetrical Internal Alkynes: Factors Governing the Regioselectivity. In ACS Catalysis (Vol. 13, Issue 15, p. 10115-10136). https://doi.org/10.1021/acscatal.3c01986
(). Facile MOF Support Improvement in Synergy with Light Acceleration for Efficient Nanoalloy-Catalyzed H2 Production from Formic Acid. In ACS Applied Materials and Interfaces (Vol. 15, Issue 19, p. 23343-23352). https://doi.org/10.1021/acsami.3c03684
(). Dramatic acceleration by visible light and mechanism of AuPd@ZIF-8-catalyzed ammonia borane methanolysis for efficient hydrogen production. In Journal of Materials Chemistry A (Vol. 11, Issue 10, p. 5245-5256). https://doi.org/10.1039/d2ta08396e
(). Fast Au-Ni@ZIF-8-catalyzed ammonia borane hydrolysis boosted by dramatic volcano-type synergy and plasmonic acceleration. In Applied Catalysis B Environmental (Vol. 320, p. 121957). https://doi.org/10.1016/j.apcatb.2022.121957
(). Recent Progress on the Mild Deprotection of Dithioketals, Dithioacetals, and Oxathiolanes. In European Journal of Organic Chemistry (Vol. 2022, Issue 7, p. e202101460). https://doi.org/10.1002/ejoc.202101460
(). Recent Advances in Synthesis of Pyrrolo[3,2-b]indole and Indolo[3,2-b]indole Derivatives. In Asian Journal of Organic Chemistry. https://doi.org/10.1002/ajoc.202200306
(). Synthesis of Oxazino[4,3-a]indoles and biological applications. In European Journal of Medicinal Chemistry (Vol. 224, p. 113728). https://doi.org/10.1016/j.ejmech.2021.113728
(). Damming an electronic energy reservoir: ion-regulated electronic energy shuttling in a [2]rotaxane. In Chemical Science (Vol. 12, Issue 26, p. 9196-9200). https://doi.org/10.1039/d1sc02225c
(). Visible-Light Acceleration of H2Evolution from Aqueous Solutions of Inorganic Hydrides Catalyzed by Gold-Transition-Metal Nanoalloys. In ACS Applied Materials and Interfaces (Vol. 12, Issue 48, p. 53816-53826). https://doi.org/10.1021/acsami.0c16247
(). Photoreversible stretching of a BAPTA chelator marshalling Ca2+-binding in aqueous media. In Beilstein Journal of Organic Chemistry (Vol. 15, p. 2801-2811). https://doi.org/10.3762/bjoc.15.273
(). Efficient “Click”-Dendrimer-Supported Synergistic Bimetallic Nanocatalysis for Hydrogen Evolution by Sodium Borohydride Hydrolysis. In Chemcatchem (Vol. 11, Issue 9, p. 2341-2349). https://doi.org/10.1002/cctc.201900246
(). Photochromic rotaxanes and pseudorotaxanes. In Photochemical and Photobiological Sciences (Vol. 18, Issue 9, p. 2102-2111). https://doi.org/10.1039/c9pp00057g
(). 13 metastable states arising from a simple multifunctional unimolecular system. In Dyes and Pigments (Vol. 137, p. 490-498). https://doi.org/10.1016/j.dyepig.2016.10.027
(). Synthetic water soluble di-/tritopic molecular receptors exhibiting Ca2+/Mg2+ exchange. In Organic and Biomolecular Chemistry (Vol. 15, Issue 20, p. 4367-4374). https://doi.org/10.1039/c6ob02732f
(). Dithienylethene-Based Gated Ambichromic Dyads. In Advanced Optical Materials (Vol. 4, Issue 9, p. 1358-1362). https://doi.org/10.1002/adom.201600233
(). Harnessing Reversible Electronic Energy Transfer: From Molecular Dyads to Molecular Machines. In Chemphyschem (Vol. 17, Issue 12, p. 1794-1804). https://doi.org/10.1002/cphc.201600137
(). Second-Order Nonlinear Optical Properties of a Dithienylethene-Indolinooxazolidine Hybrid: A Joint Experimental and Theoretical Investigation. In Chemistry A European Journal (Vol. 21, Issue 51, p. 18749-18757). https://doi.org/10.1002/chem.201502728
(). Huge electro-/photo-/acidoinduced second-order nonlinear contrasts from multiaddressable indolinooxazolodine. In Journal of Physical Chemistry B (Vol. 119, Issue 22, p. 6758-6765). https://doi.org/10.1021/acs.jpcb.5b03070
(). Indolinooxazolidine: A versatile switchable unit. In Journal of Physical Chemistry B (Vol. 119, Issue 1, p. 307-315). https://doi.org/10.1021/jp511825f
(). A simple molecule-based octastate switch. In Journal of the American Chemical Society (Vol. 136, Issue 39, p. 13510-13513). https://doi.org/10.1021/ja506320j
(). Design and characterization of molecular nonlinear optical switches. In Accounts of Chemical Research (Vol. 46, Issue 11, p. 2656-2665). https://doi.org/10.1021/ar4000955
(). Synthesis of symmetrical and nonsymmetrical bisthienylcyclopentenes. In Chemistry A European Journal (Vol. 19, Issue 34, p. 11124-11132). https://doi.org/10.1002/chem.201301645
(). Synthesis of photochromic 6-aryl-substituted bis(benzothiophenyl)- perfluorocyclopentenes by the Suzuki-Miyaura cross-coupling. In Mendeleev Communications (Vol. 23, Issue 2, p. 78-80). https://doi.org/10.1016/j.mencom.2013.03.007
(). Nonlinear optical molecular switches as selective cation sensors. In Journal of the American Chemical Society (Vol. 134, Issue 19, p. 8101-8103). https://doi.org/10.1021/ja302395f
(). Introduction to the themed issue dedicated to Jean-Pierre Desvergne. In Photochemical and Photobiological Sciences (Vol. 11, Issue 11, p. 1611-1612). https://doi.org/10.1039/c2pp90037h
(). Toward multi-addressable molecular systems: Efficient synthesis and photochromic performance of unsymmetrical bisthienylethenes. In Dyes and Pigments (Vol. 89, Issue 3, p. 246-253). https://doi.org/10.1016/j.dyepig.2010.03.018
(). Ion translocation in artificial molecule-based systems induced by light, electrons, or chemicals. In Australian Journal of Chemistry (Vol. 64, Issue 10, p. 1301-1314). https://doi.org/10.1071/CH11177
(). Editorial: Synthetic and natural photoswitches. In Photochemical and Photobiological Sciences (Vol. 9, Issue 2, p. 127). https://doi.org/10.1039/b925378p
(). Harnessing supramolecular interactions in organic solid-state devices: Current status and future potential. In Coordination Chemistry Reviews (Vol. 254, Issue 19-20, p. 2429-2445). https://doi.org/10.1016/j.ccr.2010.05.007
(). Photochromic performance of a dithienylethene-indolinooxazolidine hybrid. In Photochemical and Photobiological Sciences (Vol. 9, Issue 2, p. 131-135). https://doi.org/10.1039/b9pp00127a
(). Two-way molecular switches with large nonlinear optical contrast. In Chemistry A European Journal (Vol. 15, Issue 11, p. 2560-2571). https://doi.org/10.1002/chem.200801967
(). Theoretical investigation of the dynamic first hyperpolarizability of DHA-VHF molecular switches. In New Journal of Chemistry (Vol. 33, Issue 6, p. 1349-1356). https://doi.org/10.1039/b900432g
(). A triblock fluorous surfactant as a specific gelator for perfluorocarbons. In Chemical Communications (Issue 34, p. 5133-5134). https://doi.org/10.1039/b908820b
(). Photogeneration of an ADADA H-bonding cleft based on a naphthopyran-decorated triazine. In Journal of Photochemistry and Photobiology A Chemistry (Vol. 200, Issue 1, p. 68-73). https://doi.org/10.1016/j.jphotochem.2008.04.009
(). Photochromism of dihydroindolizines Part IX. First attempts towards efficient self-assembling organogelators based on photochromic dihydroindolizines and N-acyl-1,ω-amino acid units. In Journal of Photochemistry and Photobiology A Chemistry (Vol. 200, Issue 1, p. 57-67). https://doi.org/10.1016/j.jphotochem.2008.03.012
(). In silico optimization of merocyanine-spiropyran compounds as second-order nonlinear optical molecular switches. In Physical Chemistry Chemical Physics (Vol. 10, Issue 41, p. 6223-6232). https://doi.org/10.1039/b806561f
(). Investigation on the second-order nonlinear optical responses in the keto-enol equilibrium of anil derivatives. In Journal of Physical Chemistry C (Vol. 112, Issue 14, p. 5638-5645). https://doi.org/10.1021/jp711511t
(). Shear-induced fractures and three-dimensional motions in an organogel. In Physical Review E Statistical Nonlinear and Soft Matter Physics (Vol. 77, Issue 1, p. 011401). https://doi.org/10.1103/PhysRevE.77.011401
(). Multi-addressable supramolecular gels based on linear amino acid and bisthienylcyclopentene. In Journal of Physical Organic Chemistry (Vol. 20, Issue 11, p. 888-893). https://doi.org/10.1002/poc.1253
(). Acido-triggered nonlinear optical switches: Benzazolo-oxazolidines. In Journal of Physical Chemistry B (Vol. 111, Issue 33, p. 9795-9802). https://doi.org/10.1021/jp073386
(). Benzyl and tert-butyl carbamate derivatives of 1,ω-amino acids as simple yet efficient gelators. In Tetrahedron (Vol. 63, Issue 31, p. 7482-7488). https://doi.org/10.1016/j.tet.2007.03.126
(). 5-Nitrogenated-naphthopyrans: Toward photoinduced hydrogen-bonded complexes. In Journal of Physical Organic Chemistry (Vol. 20, Issue 11, p. 872-877). https://doi.org/10.1002/poc.1218
(). Photodimerization of soluble tetracene derivatives using visible light. In Journal of Physical Organic Chemistry (Vol. 20, Issue 11, p. 838-844). https://doi.org/10.1002/poc.1214
(). Photoresponsive gels. In Molecular Gels Materials with Self Assembled Fibrillar Networks (p. 817-855). https://doi.org/10.1007/1-4020-3689-2_25
(). Structural variations in a family of orthodialkoxyarenes organogelators. In Journal of Colloid and Interface Science (Vol. 302, Issue 2, p. 633-642). https://doi.org/10.1016/j.jcis.2006.06.056
(). Theoretical design of molecular photo- and acido-triggered non-linear optical switches. In Chemical Physics Letters (Vol. 427, Issue 1-3, p. 153-158). https://doi.org/10.1016/j.cplett.2006.06.011
(). Acidoswitchable NLO-phores; Benzimidazolo[2,3-b]oxazolidines. In Journal of Physical Chemistry B (Vol. 110, Issue 22, p. 10672-10682). https://doi.org/10.1021/jp060825g
(). Photoresponsive nanoassemblies of a dithienylethene organogelator. In Molecular Crystals and Liquid Crystals (Vol. 430, p. 99-106). https://doi.org/10.1080/15421400590946226
(). Molecular Crystals and Loquid Crystals: Guest editors' preface. In Molecular Crystals and Liquid Crystals (Vol. 430, p. ix-x). https://doi.org/10.1080/15421400590946073
(). Dyads and triads based on dithienylethene and indolino[2,1-b]oxazolidine. In Molecular Crystals and Liquid Crystals (Vol. 430, p. 37-43). https://doi.org/10.1080/15421400590946145
(). Experimental and theoretical determination of the first-order hyperpolarizability of photo- and acidochromic indolino[2,1-b]oxazolidines. In Synthetic Metals (Vol. 155, Issue 2, p. 393-397). https://doi.org/10.1016/j.synthmet.2005.09.021
(). Grafting of gold nanoparticles onto organogelator-templated fibrous mercaptosilica. In Zeitschrift Fur Anorganische Und Allgemeine Chemie (Vol. 631, Issue 11, p. 2215-2220). https://doi.org/10.1002/zaac.200570046
(). Acido- And phototriggered NLO properties enhancement. In Journal of Physical Chemistry B (Vol. 109, Issue 22, p. 11139-11150). https://doi.org/10.1021/jp0442450
(). Photoswitch based on remarkably simple naphthopyrans. In Tetrahedron Letters (Vol. 46, Issue 18, p. 3257-3259). https://doi.org/10.1016/j.tetlet.2005.02.091
(). Chiral gelators constructed from 11-aminoundecanoic (AUDA), lauric and amino acid units. Synthesis, gelling properties and preferred gelation of racemates vs. the pure enantiomers. In European Journal of Organic Chemistry (Issue 19, p. 4048-4059). https://doi.org/10.1002/ejoc.200400105
(). Thixotropic Organogels Based on a Simple N-Hydroxyalkyl Amide: Rheological and Aging Properties. In Langmuir (Vol. 20, Issue 8, p. 3032-3041). https://doi.org/10.1021/la035219g
(). 11-Aminoundecanoic acid: a versatile unit for the generation of low molecular weight gelators for water and organic solvents. In Chemical Communications (Vol. 4, Issue 2, p. 190-191). https://doi.org/10.1039/b307846a
(). 5-Ureido-3,3-diphenyl-3H-naphtho[2,1-b]pyrans: Photoswitchable self-assembling architectures. In International Journal of Photoenergy (Vol. 6, Issue 4, p. 169-173). https://doi.org/10.1155/S1110662X04000212
(). Spectroscopic properties and gelling ability of a set of rod-like 2,3-disubstituted anthracenes. In New Journal of Chemistry (Vol. 28, Issue 2, p. 234-243). https://doi.org/10.1039/b306961c
(). New acido- and photoswitchable chromophores for second-order nonlinear optics. In Journal of Nonlinear Optical Physics and Materials (Vol. 13, Issue 3-4, p. 423-426). https://doi.org/10.1142/s0218863504002055
(). One-pot synthesis of phenyl- and amine-functionalized silica fibers through the use of anthracenic and phenazinic organogelators. In Journal of Materials Chemistry (Vol. 13, Issue 10, p. 2505-2514). https://doi.org/10.1039/b304479n
(). Structural aspects of the gelation process observed with low molecular mass organogelators. In Langmuir (Vol. 19, Issue 6, p. 2013-2020). https://doi.org/10.1021/la026660u
(). Design of organically functionalised hybrid silica fibres through the use of anthracenic organogelators. In Journal of Materials Chemistry (Vol. 13, Issue 3, p. 442-444). https://doi.org/10.1039/b212465n
(). Templated growth of alumina-based fibers through the use of anthracenic organogelators. In Chemistry of Materials (Vol. 14, Issue 12, p. 5124-5133). https://doi.org/10.1021/cm021247t
(). Multiaddressable self-assembling organogelators based on 2H-chromene and N-acyl-1,ω-amino acid units. In Langmuir (Vol. 18, Issue 19, p. 7096-7101). https://doi.org/10.1021/la025545g
(). Flow-induced alignment of fiberlike supramolecular self-assemblies during organogel formation with various low molecular mass organogelator-solvent systems. In Langmuir (Vol. 18, Issue 19, p. 7151-7153). https://doi.org/10.1021/la025565i
(). Rational design of low molecular mass organogelators: Toward a library of functional N-Acyl-1,ω-amino acid derivatives. In Angewandte Chemie International Edition (Vol. 40, Issue 17, p. 3164-3166). https://doi.org/10.1002/1521-3773(20010903)40:17<3164::AID-ANIE3164>3.0.CO;2-B
(). The unusual molecular organization of 2,3-bis(n-hexyloxy)-anthracene in the crystal. A hint to the origin of the gelifying properties of 2,3-bis(n-alkyloxy)anthracenes?. In Journal of the Chemical Society Perkin Transactions 2 (Issue 5, p. 824-826). https://doi.org/10.1039/b008084p
(). Excimer fluorescence of a new bisanthracene as probe of viscosity in polysiloxanes. In Polycyclic Aromatic Compounds (Vol. 18, Issue 3, p. 293-306). https://doi.org/10.1080/10406630108033063
(). New organogelators based on linear azapolycyclic arenes. In Polycyclic Aromatic Compounds (Vol. 19, Issue 1-4, p. 107-117). https://doi.org/10.1080/10406630008034726
(). Photochromic guests in organogels. In Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals (Vol. 344, p. 101-106). https://doi.org/10.1080/10587250008023821
(). Organogelators for malting porous sol-gel derived silica at two different length scales. In Journal of Materials Chemistry (Vol. 10, Issue 7, p. 1725-1730). https://doi.org/10.1039/b000525h
(). Remarkably simple small organogelators: Di-n-alkoxy-benzene derivatives. In Tetrahedron Letters (Vol. 40, Issue 51, p. 9021-9024). https://doi.org/10.1016/S0040-4039(99)01918-8
(). Photochromic cooligomers from pyridazinespirodihydroindolizine and styrene. In Journal of Materials Chemistry (Vol. 9, Issue 9, p. 2245-2250). https://doi.org/10.1039/a900066f
(). Photochromic properties of spiro[fluorene-chromenes]. In Acta Crystallographica Section C Crystal Structure Communications (Vol. 54, Issue 11, p. 1720-1722). https://doi.org/10.1107/S0108270198004727
(). Effect of heteroaromatic annulation with five-membered rings on the photochromism of 2H-[1]-benzopyrans. In Journal of Photochemistry and Photobiology A Chemistry (Vol. 114, Issue 3, p. 185-191). https://doi.org/10.1016/S1010-6030(98)00215-9
(). Rational design of new acid-sensitive organogelators. In Journal of Materials Chemistry (Vol. 8, Issue 12, p. 2575-2577). https://doi.org/10.1039/a807237j
(). 2,3-Di-n-alkoxyanthraquinones as gelators of organic solvents. In Journal of the Chemical Society Perkin Transactions 2 (Issue 11, p. 2527-2534). https://doi.org/10.1039/a803302a
(). Different synthetic routes towards efficient organogelators: 2,3-substituted anthracenes. In Tetrahedron (Vol. 53, Issue 18, p. 6377-6390). https://doi.org/10.1016/S0040-4020(97)00297-4
(). Synthesis and Photochromic Behaviour of Naphthopyrans, Pyranoquinolines, Pyranoquinazolines and Pyranoquinoxalines. In Helvetica Chimica Acta (Vol. 80, Issue 3, p. 725-738). https://doi.org/10.1002/hlca.19970800310
(). 'Living' free-radical polymerization process: A new approach towards well-defined photochromic (co)polymers. In Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals (Vol. 297-298, p. 161-167). https://doi.org/10.1080/10587259708036156
(). Spiro[2H]-1-benzopyran-2,9′-fluorenes: Hyperchromic and bathochromic shifts of the visible absorption of chromenes. In Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals (Vol. 297-298, p. 255-262). https://doi.org/10.1080/10587259708036130
(). Specific structural features and photochemical properties of three benzo-annulated 2,2-diphenyl[2H]chromenes. In Acta Crystallographica Section C Crystal Structure Communications (Vol. 52, Issue 7, p. 1834-1838). https://doi.org/10.1107/S0108270195016209
(). Photochromic pyrido-annelated 2,2-dimethylchromene. In Acta Crystallographica Section C Crystal Structure Communications (Vol. 52, Issue 6, p. 1537-1539). https://doi.org/10.1107/S0108270195016192
(). Furo-fused 2H-chromenes: Synthesis and photochromic properties. In Canadian Journal of Chemistry (Vol. 74, Issue 9, p. 1649-1659). https://doi.org/10.1139/v96-182
(). New Photochromic 2,2-Diphenyl-[2H]-Chromenes Annellated with Nitrogenated Six-Membered Ring. In Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals (Vol. 246, Issue 1, p. 75-78). https://doi.org/10.1080/10587259408037791
(). A convenient synthesis of azolo-fused 2H-[1] benzopyrans. In Journal of the Chemical Society Perkin Transactions 1 (p. 2591-2595). https://doi.org/10.1039/P19940002591
(). Solvatochromie and photochromie characteristics of new 1,3-dihydrospiro[2H-indole-2,2′-[2H]-bipyrido[3,2-f][2,3-h][1,4]benzoxazines]. In Journal of the Chemical Society Perkin Transactions 2 (Issue 7, p. 1327-1332). https://doi.org/10.1039/P29930001327